Product ID:SUN LARGE TABLETS, CPE 710129
MSDS Date:03/01/1989
FSC:6850
NIIN:00N048895
MSDS Number: BVHTL

OLIN CORP

120 LONG RIDGE RD
STAMFORD, CT 06904
US

Emergency Phone: 800-654-6911

Info Phone: 203-356-3449

Cage: 8X135

OLIN CORP CHEMICALS GROUP

STAMFORD, CT 06904 US

Telephone: 203-356-3449,CHEMTREC 800-242-9300

Cage: 53084

CLTHG, I.E. CHEM IMPERMEABLE SUIT. COMPAT MATLS FOR

RTECS: 9999999ZZ

POLYETHYLENE, BUTYL RUBBER & SARANEX.

RTECS: 9999999ZZ

UNUSED MATL, RESIDUES & CNTNRS I/A/W ALL

RTECS: 9999999ZZ

TREATMENT, STORAGE & DISPOSAL FOR HAZARDOUS &

RTECS: 9999999ZZ

S-TRIAZINE-2,4,6(1H,3H,5H)-TRIONE, 1,3-DICHLORO-;

CAS: 2782-57-2

RTECS: XZ1845000

Fraction By Weight: 0-4%

OSHA PEL N/K

ACGIH TLV: N/K

VOMIT, DIARR, ABDOM PAIN, BLEEDING &/OR TISS

RTECS: 9999999ZZ

OF LUNG FUNC & PERM LUNG DMG. EFTS FROM SKIN EXPOS

RTECS: 9999999ZZ

IF EXPERIENCE NAUS,

RTECS: 9999999ZZ

DISAPPEAR. IF BRTHG DFCLT, ADMIN OXYGEN, KEEP WARM &

RTECS: 9999999ZZ

CONSCIOUSNESS, MOVE TO FRESH AIR AT ONCE & CALL MD

RTECS: 9999999ZZ

IMMED. IN ALL CASES, ENSURE ADEQ VENT & PROVIDE RESP

RTECS: 9999999ZZ

MATL IS

RTECS: 9999999ZZ

SOURCE AS SOON AS POSS. BEGIN MONITORING FOR AVAIL

RTECS: 9999999ZZ

MATL W/ANY ORG MATLS, AMMONIA, AMMONIUM SALTS/UREA.

RTECS: 9999999ZZ

DISPOSE OF PER

RTECS: 9999999ZZ

BEFORE BEGINNING ANY SUCH OPERATION. PERSONAL

RTECS: 9999999ZZ

MASK CARTRIDGE TYPE NIOSH/MSHA APPRVD RESP

RTECS: 9999999ZZ

SCBA. ADDNL PROT CLTHG INCL BUT NOT LIMITED TO

RTECS: 9999999ZZ

S-TRIAZINE-2,4,6(1H,3H,56)-TRIONE, 1,3,5-TRICHLORO-;

CAS: 87-90-1

RTECS: XZ1925000

Fraction By Weight: 96-100%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50: (ORAL, RAT) 490 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHAL/INGEST/EXPOS TO
SKIN/EYES. INHAL:IRRIT TO NOSE, MOUTH, THROAT & LUNGS. MAY CAUSE
BURN TO RESP TRACT W/LUNG EDEMA WHICH CAN RSLT IN SHORTNESS OF
BREATH, WHEEZ, CHOKING, CHEST PAIN & IM PAIRMENT OF LUNG FUNC.
INHAL OF HIGH CONC CAN RSLT IN PERM LUNG DMG. EYES: SEV IRRIT &/OR
BURNS CAN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CAN OCCUR. CNTCT MAY CAUSE VISION
IMPAIRMENT & CORNEAL DMG. SKIN:CAN CAUSE SEV IRRIT &/OR BURNS
CHARACT BY REDNESS, SWELL & SCAB FORM. PRLNG EXPOS MAY CAUSE
DESTRUCT OF DERMIS W/IMPAIRMENT O F SKIN AT SITE OF CNTCT TO
REGENERATE. INGEST:IRRIT &/OR BURNS CAN OCCUR TO GI TRACT, INCL
STOM & INTESTINES, (SUPDAT)
Medical Cond Aggravated by Exposure:ASTHMA AND RESPIRATORY AND
CARDIOVASCULAR DISEASE.

First Aid:EYES: IMMED FLUSH W/LG AMTS WATER FOR @ LEAST 15 MIN, OCCAS
LIFTING UPPER & LOWER LIDS. CALL MD AT ONCE. SKIN: IMMED FLUSH
W/WATER FOR @ LEAST 15 MIN. CALL MD. IF CLTHG COMES IN CNTCT
W/PROD, CLTHG SH OULD BE REMOVED IMMED & SHOULD BE LAUNDERED BEFORE
REUSE. INGEST: IMMED DRINK LG QTYS WATER. DO NOT INDUCE VOMIT. CALL
MD AT ONCE. DO NOT GIVE ANYTHING BY MOUTH IF PERSON IS UNCON/HAVING
(ING 5)

Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP USE
H*2O TO COOL CNTNR EXPOS TO FIRE. ON SM FIRES, USE H*2O SPRAY/FOG.
ON LG FIRES, USE HVY DELUGE FOG/ (SUPDAT)
Unusual Fire/Explosion Hazard:IF THIS MATERIAL BECOMES
DAMP/WET/CONTAMINATED IN A CONTAINER THE FORMATION OF NITROGEN
TRICHLORIDE GAS MAY OCCUR AND AN EXPLOSIVE CONDITION MAY EXIST.

Spill Release Procedures:HAZ CONC IN AIR MAY BE FOUND IN LOCAL SPILL
AREA & IMMED DOWNWIND. IF SPILL MATL STILL DRY, DO NOT PUT WATER
DIRECTLY ON PROD AS GAS EVOLUTION MAY OCCUR. IF MATL WET, CNTCT MFR
FOR PROPER STABILIZATIO N PROC. AIR RELS:VAPS MAY BE SUPPRESSED(ING
9)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN CLEAN, DRY, WELL VENTILATED
AREA. KEEP AWAY FROM INCOMPATIBLE CHEMICALS. DO NOT STORE ABOVE
140F (60C).
Other Precautions:INDEFINITE SHELF LIFE. AVAILABLE CHLORINE LOSS CAN BE
AS LITTLE AS 0.1% PER YEAR AT AMBIENT TEMPERATURES. DO NOT TAKE
INTERNALLY. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. UPON
CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR EQUIPPED
WITH CHEMICAL CARTRIDGE FOR PROTECTION AGAINST CHLORINE GAS & A
DUST/MIST TYPE PREFILTER.
Ventilation:USE LOCAL EXHAUST VENTILATION TO MAINTAIN DUST LEVELS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORK GOG (WORK HYGIENE)
Other Protective Equipment:WEAR NEOPRENE BOOTS, NEOPRENE APRONS OR
NEOPRENE/OTHER IMPERMEABLE SUIT TO AVOID SKIN CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. EYE
PROTECTION: WITH FULL LENGTH FACESHIELD .
Supplemental Safety and Health
PH: 2.7-2.9 (1% SOLN). FIRE FIGHT PROC: STREAMS. FLOODING AMTS OF WATER
MAY BE REQD BEFORE EXTING CAN BE ACCOMPLISHED. DO NOT USE DRY CHEM
EXTING CNTN AMMONIA CMPDS. CNDTNS TO AVOID: WET PROD (WILL RL S
NITROGEN TRICHLORIDE). MATLS TO AVOID: DRY FIRE EXTING CNTN
AMMONIUM CMPDS. EFTS OF OVEREXP: CHARACT BY NAUS, (ING 3)

HCC:D1
Decomp Temp:Decomp Text:437F,225C
Spec Gravity:>1 @ 20C
pH:SUPDAT
Solubility in Water:1.2% @ 25C
Appearance and Odor:WHITE GRANULAR SOLID OR TABLET-FORM PRODUCT; SHARP,
CHLORINE-LIKE, BLEACH ODOR.

Stability Indicator/Materials to Avoid:YES
ORG MATLS, OILS, GREASE, SAWDUST, REDUCING AGENTS, NITROGEN CONTAINING
CMPDS, OTHER OXIDIZERS, ACIDS, BASES, (SUPDAT)
Stability Condition to Avoid:TEMP > 437F (225C). CNTCT W/SM AMTS WATER
MAY RSLT IN EXOTHERMIC RXN W/LIBERATION OF TOX FUMES. DAMP/SLIGHTLY
(SUPDAT)
Hazardous Decomposition Products:NITROGEN TRICHLORIDE, CHLORINE,
NITROUS OIXDES, CYANATES, CARBON MONOXIDE, CARBON DIOXIDE.

Waste Disposal Methods:HAZ WASTE NUMBER:D001. MUST BE DISP OF I/A/W
LOCAL, STATE & FED REGS IN PERMITTED HAZ WASTE TREATMENT, STORAGE &
DISPOS FACILITY BY TREATMENT. CARE MUST BE TAKEN TO PVNT ENVIRON
CONTAM FROM USE OF MAT L. USER HAS RESPONSIBILITY TO DISPOSE OF
(ING 18)

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of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.